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Class 12 chemistry guess paper 2025

JKBOSE Class 12 Chemistry Guess paper 2025

JKBOSE Class 12 Chemistry Guess paper 2025 syllabus and the unit-wise weightage, here’s a guess paper for the upcoming exam. This guess paper is designed to cover high-weightage topics and frequently asked questions.


JKBOSE Class 12 Chemistry Guess paper 2025

Unit-I: SOLUTIONS (7 Marks)

  1. Very Short Answer (1 mark)
    • Define colligative properties.
    • What is Van’t Hoff factor?
  2. Short Answer I (2 marks)
    • Derive the expression for relative lowering of vapor pressure.
    • Calculate the molecular mass of a solute if the osmotic pressure of its solution is given.
  3. Long Answer (4 marks)
    • Explain Raoult’s law and its limitations. Derive the expression for elevation in boiling point.

Unit-II: ELECTROCHEMISTRY (9 Marks)

  1. Very Short Answer (1 mark)
    • What is the standard hydrogen electrode (SHE)?
    • Define molar conductivity.
  2. Short Answer I (2 marks)
    • State Kohlrausch’s law of independent migration of ions.
    • Write the Nernst equation and explain its terms.
  3. Short Answer II (3 marks)
    • Explain the working of a lead-acid battery with a diagram.
    • Calculate the emf of a cell using the Nernst equation.
  4. Long Answer (5 marks)
    • Derive the relationship between Gibbs energy change and emf of a cell. Discuss the applications of fuel cells.

Unit-III: CHEMICAL KINETICS (7 Marks)

  1. Very Short Answer (1 mark)
    • Define the rate of reaction.
    • What is the half-life period of a reaction?
  2. Short Answer I (2 marks)
    • Derive the integrated rate equation for a first-order reaction.
    • Explain the effect of temperature on the rate of reaction using the Arrhenius equation.
  3. Long Answer (4 marks)
    • Discuss the collision theory of chemical reactions. Derive the expression for the rate constant of a zero-order reaction.

Unit-IV: d and f-BLOCK ELEMENTS (7 Marks)

  1. Very Short Answer (1 mark)
    • What is lanthanide contraction?
    • Why are transition metals good catalysts?
  2. Short Answer I (2 marks)
    • Explain the preparation of K₂Cr₂O₇ from chromite ore.
    • Discuss the magnetic properties of transition metals.
  3. Long Answer (4 marks)
    • Compare the properties of lanthanides and actinides. Explain the catalytic properties of transition metals.

Unit-V: CO-ORDINATION COMPOUNDS (7 Marks)

  1. Very Short Answer (1 mark)
    • What is a ligand? Give an example.
    • Define coordination number.
  2. Short Answer I (2 marks)
    • Explain Werner’s theory of coordination compounds.
    • Write the IUPAC name of [Co(NH₃)₆]Cl₃.
  3. Long Answer (4 marks)
    • Discuss the bonding in coordination compounds using Valence Bond Theory (VBT). Explain the importance of coordination compounds in biological systems.

Unit-VI: HALOALKANES AND HALOARENES (6 Marks)

  1. Very Short Answer (1 mark)
    • What is the nature of the C-X bond in haloalkanes?
    • Give the structure of iodoform.
  2. Short Answer I (2 marks)
    • Explain the mechanism of SN2 reaction in haloalkanes.
    • Discuss the environmental effects of DDT.
  3. Long Answer (3 marks)
    • Compare the reactivity of haloalkanes and haloarenes towards nucleophilic substitution reactions.

Unit-VII: ALCOHOLS, PHENOLS AND ETHERS (6 Marks)

  1. Very Short Answer (1 mark)
    • What is the acidic nature of phenol?
    • Give the structure of methanol.
  2. Short Answer I (2 marks)
    • Explain the mechanism of dehydration of alcohols.
    • Discuss the electrophilic substitution reactions of phenol.
  3. Long Answer (3 marks)
    • Compare the physical and chemical properties of alcohols and phenols.

Unit-VIII: ALDEHYDES, KETONES AND CARBOXYLIC ACIDS (8 Marks)

  1. Very Short Answer (1 mark)
    • What is the reactivity of alpha hydrogen in aldehydes?
    • Give the structure of acetic acid.
  2. Short Answer I (2 marks)
    • Explain the nucleophilic addition reaction in carbonyl compounds.
    • Discuss the Hell-Volhard-Zelinskii reaction.
  3. Long Answer (5 marks)
    • Compare the physical and chemical properties of aldehydes and ketones. Explain the mechanism of aldol condensation.

Unit-IX: ORGANIC COMPOUNDS CONTAINING NITROGEN (6 Marks)

  1. Very Short Answer (1 mark)
    • What is diazotization?
    • Give the structure of aniline.
  2. Short Answer I (2 marks)
    • Explain the Hoffmann bromamide reaction.
    • Discuss the basicity of amines.
  3. Long Answer (3 marks)
    • Compare the physical and chemical properties of primary, secondary, and tertiary amines.

Unit-X: BIOMOLECULES (7 Marks)

  1. Very Short Answer (1 mark)
    • What are reducing sugars?
    • Define denaturation of proteins.
  2. Short Answer I (2 marks)
    • Explain the structure of glucose.
    • Discuss the functions of nucleic acids.
  3. Long Answer (4 marks)
    • Compare the structures of DNA and RNA. Explain the importance of vitamins in the human body.

Tips for Preparation

  1. Focus on NCERT: All questions are based on NCERT concepts.
  2. Practice Numericals: Especially from Solutions, Electrochemistry, and Chemical Kinetics.
  3. Revise Named Reactions: Mechanisms and distinguishing tests.
  4. Memorize Structures: Biomolecules (glucose, DNA), coordination geometries.
Naming Reactions – Class 12

Important Naming Reactions – Class 12 (JKBOSE)

Equation: 2C6H5CHO + NaOH → C6H5CH2OH + C6H5COONa

Explanation: Aldehydes without α-hydrogen undergo self-oxidation and reduction in the presence of a strong base.

Equation: RCOR’ + Zn(Hg) + HCl → RCH2R’ + ZnCl2

Explanation: This reaction reduces ketones and aldehydes to alkanes using zinc amalgam and concentrated HCl.

Equation: RCOR’ + NH2NH2 + KOH → RCH2R’ + N2

Explanation: Carbonyl compounds are reduced to hydrocarbons using hydrazine and a strong base.

Equation: C6H6 + RCl + AlCl3 → C6H5R + HCl

Explanation: An alkyl group is added to benzene using an alkyl halide in the presence of AlCl3.

Equation: C6H5OH + CHCl3 + NaOH → o-HO-C6H4-CHO + HCl

Explanation: Phenol reacts with chloroform and NaOH to form salicylaldehyde.

Equation: 2CH3CHO → CH3CH(OH)CH=CH2

Explanation: Aldehydes and ketones with α-hydrogen undergo condensation in base to form β-hydroxy aldehydes or ketones.

Equation: C6H5CHO + CH3COOCH3 → C6H5CH=CHCOOH

Explanation: Aldehydes react with acid anhydrides to form α,β-unsaturated acids.

Equation: C6H5Cl + Na + C6H5Cl → C6H5-C6H5 + NaCl

Explanation: Aryl halides react with sodium metal to form biaryl compounds.

Equation: C6H5N2Cl + CuCl → C6H5Cl + N2

Explanation: Aromatic diazonium salts react with CuCl or CuBr to form aryl halides.

Equation: C6H5ONa + CO2 → C6H4(OH)COOH

Explanation: Phenol reacts with CO2 in the presence of NaOH to form salicylic acid.

Additional Naming Reactions – Class 12

Additional Naming Reactions – Class 12 (JKBOSE)

Equation: CH3COOH + Br2 + P → CH2BrCOOH + HBr

Explanation: Carboxylic acids with α-hydrogen react with bromine in the presence of phosphorus to form α-bromo acids.

Equation: C6H6 + CO + HCl → C6H5CHO

Explanation: Benzene reacts with CO and HCl in the presence of AlCl3 and CuCl to form benzaldehyde.

Equation: RCOCl + H2 + Pd/BaSO4 → RCHO + HCl

Explanation: Acid chlorides are reduced to aldehydes using hydrogen in the presence of palladium catalyst.

Equation: C6H5CH3 + CrO2Cl2 → C6H5CHO

Explanation: Toluene is oxidized to benzaldehyde using chromyl chloride.

Equation: RCN + SnCl2 + HCl → RCH=NH → RCHO

Explanation: Nitriles are reduced to aldehydes using SnCl2 and HCl.

Equation: RCl + 2Na + R’Cl → R-R’ + 2NaCl

Explanation: Alkyl halides react with sodium metal in dry ether to form higher alkanes.

Equation: R2CuLi + R’X → R-R’ + RCu + LiX

Explanation: Alkyl halides react with lithium dialkylcuprates to form higher alkanes.

Equation: RCl + NaI → RI + NaCl

Explanation: Alkyl chlorides and bromides are converted to alkyl iodides using sodium iodide in acetone.

Equation: C6H5N2Cl → C6H5F + N2 + Cl2

Explanation: Aromatic diazonium salts are converted to aryl fluorides using fluoroboric acid.

Equation: Phthalimide + KOH + R-X → R-NH2

Explanation: Primary amines are synthesized from alkyl halides via phthalimide.

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